Question

Consider a system with three discrete energy levels: ?0, ?1 and ?2 with degeneracies of 1, 3 and 5, respectively. Write the expression for the molecular partition function (q) for this system.

19 Aug 2026
Answer :
Word Count : 573
# Molecular Partition Function for a Three-Level System In statistical thermodynamics, the molecular partition function is a fundamental quantity used to describe the distribution of molecules among the available energy states of a system. It provides a connection between the microscopic energy levels of individual molecules and the macroscopic thermodynamic properties of the system. For a system having discrete energy levels, the molecular partition function is obtained by summing the Boltzmann factors of all possible states, taking their degeneracies into account. For a system with three discrete energy levels, denoted by (E_0), (E_1), and (E_2), the corresponding degeneracies are given as 1, 3, and 5, respectively. The degeneracy of an energy level represents the number of distinct quantum states that possess the same energy. Thus, the lowest energy level (E_0) has one state, (E_1) has three states, and (E_2) has five states. For a molecule in thermal equilibrium at temperature (T), the probability of occupying a particular state of energy (E_i) is proportional to the Boltzmann factor, [ e^{-E_i/k_BT}, ] where (k_B) is the Boltzmann constant and (T) is the absolute temperature. The general expression for the molecular partition function for discrete energy levels is [ q=\sum_i g_i e^{-E_i/k_BT}, ] where (g_i) is the degeneracy of the (i)-th energy level and (E_i) is its energy. For the present three-level system, [ g_0=1,\qquad g_1=3,\qquad
___ __________ ______ ____ _____ _________ _________.
_________ ______ __________ _____ ________ ____ __________ _____ _________ _______.
________ ___ ______ ________ __________ ______.
_____ ___ _______ _______ _________ _______ ___ _________ ________ _______ ______ ___.
_________ ______ _______ ____ _____ ______.
__________ ________ __________ ______ _________ __________ __________ __________ _________ __________.
_________ __________ _________ ____ _________ _____ _______.
________ _____ __________ ___ _______ ___ ____ ________ ________ ______.
______ ______ _______ _____ _____ ___ __________ ______ _______ _____ _____ _____.
________ ______ ____ ___ ____ _____ __________ ________ __________ ___.
_________ __________ _________ ______ ____ ___ ___ ____ _____ ________ _______.
______ __________ _________ ____ __________ __________ ___ _____.
__________ _______ ___ ________ ________ _________ __________ _______ ______.
________ ________ __________ __________ ______ ________.
____ _________ ____ ________ _________ ____.
____ ____ ________ ___ _______ ________ _________ _________.
_______ _________ ___ ____ _______ _________ ______ ________ _________.
_______ _____ ___ ___ ________ _______ ______ _______ ________ ______.
___ ___ ____ _________ _____ ________ ______ ____ _________ _______.
_______ __________ ________ ________ ________ __________ __________.
_________ _______ _____ ___ ___ ____ _______ _____ ____.
________ ________ __________ ______ ___ _______ _________ ____ ________ __________ _____.
________ _____ ___ ________ ____.
_________ ________ ____ __________ ___ ___ ____ ____ ______ ______ __________.
__________ ____ _______ _______ ________ _____ ___ _________ ______ ______.
________ ____ __________ ____ __________ ___ _________ __________ __________ __________ _________ _________.
__________ ____ ____ ______ _______.
__________ ________ ________ ____ ______ ________ ___ ____ _____.
____ ____ _______ _______ _______ _______ ______ ______.
____ ____ _______ ______ ____ _____ ___ ______ _______.
__________ ______ _______ __________ _________ _________ _______ __________ ____ _________ ____ ___.
____ _____ _________ _____ _____ ____ ________ __________ _________.
__________ ____ ______ ________ ____ ___.
______ _______ _________ _________ ______ ________ _____ __________ _______ _________.
_____ _______ _____ ______ ____ _______ _____ _____ _______.
__________ __________ __________ _______ _______ _______ ____ ________ ______ ______ _____ _______.
_______ _________ ___ ____ ________ _____ ________ _______ ___ _____ __________ ______.
__________ ________ ________ __________ ___ _____ ________ ____ ________ ___ ____.
________ ______ ______ ________ ___ __________.
IGNOU ACADEMY
Your IGNOU journey, made easier.
  • Solved Assignments
  • Study Notes
  • Guess Papers
  • Question Papers
Skip in 10
Top
📞
Call Support Instant phone assistance IGNOU MCH 13 2026 2027 - Consider a system with three discrete energy levels: ?0, ?1 and ?2 wit | IGNOU Academy
→
🟢
WhatsApp Chat Fast live messaging
→
Email Us Business enquiries & support
→