IGNOU BCHCT 135 SOLVED ASSIGNMENT HINDI

Ques 1.

. Define the following terms:

(i) Molarity (M)

(ii) Molality (m)

 (iii) Normality (N)

(iv) Mole fraction (x)

(v) Parts per million

Also give their units.

Ques 2.

State Raoult's Law. Also, give its mathematical form.

Ques 3.

) Give any two applications of solvent extraction.

Ques 4.

 Draw and explain the mutual miscibility curve for phenol - water system.

Ques 5.

) Discuss the effect of impurities on CST values.

Ques 6.

 Define the following terms:

(i) Phase

(ii) Components

(iii) Degrees of freedom

Ques 7.

Write the integrated form of Clausius-Clapeyron equation. What were the two assumptions made by Clausius?

Ques 8.

 Draw and explain the phase diagram of water highlighting its important features.

Ques 9.

Define conductivity and give its units.

Ques 10.

The conductivity of a 0.1 M aqueous solution of acetic acid is found to be 5.3 x 104S cm. Calculate the molar conductivity of acetic acid solution at the given concentration.

Ques 11.

 Explain ionic mobility and give its units. Briefly explain the factors affecting it.

Ques 12.

 List the applications of conductivity measurement.

Ques 13.

Draw the schematic diagram of a Daniell cell and give the reactions taking place at the electrodes.

Ques 14.

 What are the functions of a salt bridge?

Ques 15.

 Give an example of a concentration cell with transference.

Ques 16.

 What is quinhydrone electrode? Give its advantageous and disadvantageous.

Ques 17.

Discuss any two applications of electrolysis.

Ques 18.

Briefly explain the process of electrolysis.

Ques 19.

. Explain the mechanism of Fischer esterfication reaction.

Ques 20.

Arrange the different carboxylic acid derivatives in the decreasing order of their reactivity towards nucleophilic substituted reactions and give reason for your answer.

Ques 21.

What is Rosenmund reduction? Give an appropriate example for this reaction.

Ques 22.

Curtius rearrnagement

Ques 23.

Schmidt rearrangement

Ques 24.

Write the products of reduction of nitrobenzene in basic medium under different conditions.

Ques 25.

) ethanamine

Ques 26.

 benzenamine

Ques 27.

What is reductive amination? Give the product of the reductive amination of diazonium salt formed by 2,4,6-tribromoaniline.
15. Explain the products formed by the nitrosation reactions of primary, secondary and tertiary amines.

Ques 28.

How will you obtain valine using Gabriel phthalimide synthesis? Explain.

Ques 29.

How will you detect a 2-amino acid using ninhydrin?

Ques 30.

 Discuss Edman degradation of N-terminal identification of peptides giving suitable reactions.

Ques 31.

 Briefly describe the primary, secondary, tertiary and quaternary structures of the peptides and proteins.

Ques 32.

Write the Fischer projection of D-glucose. Also write the Haworth projections of a-D-glucose and ẞ-D-glucofuranose.

Ques 33.

Explain mutarotation using glucose as the example.

Ques 34.

) Write the structures of ẞ-lactose and sucrose with appropriate labelling.

Ques 35.

Differentiate between amylose and amylopectin.

Ques 36.

. Define the following terms:

(i) Molarity (M)

(ii) Molality (m)

 (iii) Normality (N)

(iv) Mole fraction (x)

(v) Parts per million

Also give their units.

Ques 37.

State Raoult's Law. Also, give its mathematical form.

Ques 38.

) Give any two applications of solvent extraction.

Ques 39.

 Draw and explain the mutual miscibility curve for phenol - water system.

Ques 40.

) Discuss the effect of impurities on CST values.

Ques 41.

 Define the following terms:

(i) Phase

(ii) Components

(iii) Degrees of freedom

Ques 42.

Write the integrated form of Clausius-Clapeyron equation. What were the two assumptions made by Clausius?

Ques 43.

 Draw and explain the phase diagram of water highlighting its important features.

Ques 44.

Define conductivity and give its units.

Ques 45.

The conductivity of a 0.1 M aqueous solution of acetic acid is found to be 5.3 x 104S cm. Calculate the molar conductivity of acetic acid solution at the given concentration.

Ques 46.

 Explain ionic mobility and give its units. Briefly explain the factors affecting it.

Ques 47.

 List the applications of conductivity measurement.

Ques 48.

Draw the schematic diagram of a Daniell cell and give the reactions taking place at the electrodes.

Ques 49.

 What are the functions of a salt bridge?

Ques 50.

 Give an example of a concentration cell with transference.

Ques 51.

 What is quinhydrone electrode? Give its advantageous and disadvantageous.

Ques 52.

Discuss any two applications of electrolysis.

Ques 53.

Briefly explain the process of electrolysis.

Ques 54.

. Explain the mechanism of Fischer esterfication reaction.

Ques 55.

Arrange the different carboxylic acid derivatives in the decreasing order of their reactivity towards nucleophilic substituted reactions and give reason for your answer.

Ques 56.

What is Rosenmund reduction? Give an appropriate example for this reaction.

Ques 57.

Curtius rearrnagement

Ques 58.

Schmidt rearrangement

Ques 59.

Write the products of reduction of nitrobenzene in basic medium under different conditions.

Ques 60.

) ethanamine

Ques 61.

 benzenamine

Ques 62.

What is reductive amination? Give the product of the reductive amination of diazonium salt formed by 2,4,6-tribromoaniline.
15. Explain the products formed by the nitrosation reactions of primary, secondary and tertiary amines.

Ques 63.

How will you obtain valine using Gabriel phthalimide synthesis? Explain.

Ques 64.

How will you detect a 2-amino acid using ninhydrin?

Ques 65.

 Discuss Edman degradation of N-terminal identification of peptides giving suitable reactions.

Ques 66.

 Briefly describe the primary, secondary, tertiary and quaternary structures of the peptides and proteins.

Ques 67.

Write the Fischer projection of D-glucose. Also write the Haworth projections of a-D-glucose and ẞ-D-glucofuranose.

Ques 68.

Explain mutarotation using glucose as the example.

Ques 69.

) Write the structures of ẞ-lactose and sucrose with appropriate labelling.

Ques 70.

Differentiate between amylose and amylopectin.

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