Question

Show that for a cyclic process involving isothermal reversible expansion and
reversible compression, the total entropy change is zero.

24 Jan 2018
Answer :
Word Count : 557

Irreversible isothermal compression

The irreversible compression of the gas proceeds in one step against a constant external pressure of 3.0atm. The work is given by

w = -PextΔV = 0.060 Latm

The work done on the gas is positive because the gas is compressed; the surroundings do positive work on the gas.

How do we compute the heat added to the gas? Indirectly! We note that the process is isothermal. The total energy of the ideal gas is

ΔE = n cVΔT

and since the temperature is constant, ΔT=0 and ΔE=0. Using the first law of thermodynamics

ΔE = q + w

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