IGNOU BSCG BCHCT 135 Solutions, Phase equilibrium, Conductance, Electrochemistry and Functional Group Organic Chemistry-I Solved Assignment English

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Title Name	IGNOU BSCG BCHCT 135 Solutions, Phase equilibrium, Conductance, Electrochemistry and Functional Group Organic Chemistry-I Solved Assignment English
Type	Soft Copy (E-Assignment) .pdf
University	IGNOU
Degree	BACHELOR DEGREE PROGRAMMES
Course Code	BSCG
Course Name	Bachelor of Science
Subject Code	BCHCT 135
Subject Name	Solutions, Phase equilibrium, Conductance, Electrochemistry and Functional Group Organic Chemistry-I
Year	2026
Session	-
Language	English
Assignment Code	BCHCT 135/Assignment-1/2026
Product Description	Assignment of BSCG (Bachelor of Science) 2026. Latest BCHCT 135 2026 Solved Assignment Solutions
Format	Ready-to-Print PDF (.soft copy)

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BCHCT 135 2026 - English

ASSIGNMENT

Solutions, Phase Equilibrium, Conductance, Electrochemistry & Functional

Group Organic Chemistry-II

Core Course in Chemistry

Course Code: BCHCT-135

Assignment Code: BCHCT-135/TMA/2026

Note: Attempt all questions. The marks for each question are indicated against it.

PART-(A)

1. Define the following terms:

(i) Molarity (M)

(ii) Molality (m)

(iii) Normality (N)

(iv) Mole fraction (x)

(v) Parts per million

Also give their units.

2. (a) State Raoult's Law. Also, give its mathematical form.

(b) Give any two applications of solvent extraction.

3. (a) Draw and explain the mutual miscibility curve for phenol - water system.

(b) Discuss the effect of impurities on CST values.

4. (a) Define the following terms:

(i) Phase

(ii) Components

(iii) Degrees of freedom

(b) Write the integrated form of Clausius-Clapeyron equation. What were the two assumptions made by Clausius?

5. Draw and explain the phase diagram of water highlighting its important features.

6. (a) Define conductivity and give its units.

(b) The conductivity of a 0.1 M aqueous solution of acetic acid is found to be 5.3 x 104S cm. Calculate the molar conductivity of acetic acid solution at the given concentration.

7. (a) Explain ionic mobility and give its units. Briefly explain the factors affecting it.

(b) List the applications of conductivity measurement.

8. (a) Draw the schematic diagram of a Daniell cell and give the reactions taking place at the electrodes.

(b) What are the functions of a salt bridge?

9. (a) Give an example of a concentration cell with transference.

(b) What is quinhydrone electrode? Give its advantageous and disadvantageous.

10. (a) Discuss any two applications of electrolysis.

(b) Briefly explain the process of electrolysis.

PART-(B)

11. Explain the mechanism of Fischer esterfication reaction.

12. (a) Arrange the different carboxylic acid derivatives in the decreasing order of their reactivity towards nucleophilic substituted reactions and give reason for your answer.

(b) What is Rosenmund reduction? Give an appropriate example for this reaction.
13. (a) Briefly explain the following reactions:

(i) Curtius rearrnagement

(ii) Schmidt rearrangement

(b) Write the products of reduction of nitrobenzene in basic medium under different conditions.

14. What is diazotisation reaction? Give the products formed by the diazotisation of the following

(i) ethanamine

(ii) benzenamine

(b) What is reductive amination? Give the product of the reductive amination of diazonium salt formed by 2,4,6-tribromoaniline.
15. Explain the products formed by the nitrosation reactions of primary, secondary and tertiary amines.

16. (a) How will you obtain valine using Gabriel phthalimide synthesis? Explain.
(b) How will you detect a 2-amino acid using ninhydrin?

17. Discuss Edman degradation of N-terminal identification of peptides giving suitable reactions.
18. Briefly describe the primary, secondary, tertiary and quaternary structures of the peptides and proteins.

19. (a) Write the Fischer projection of D-glucose. Also write the Haworth projections of a-D-glucose and ẞ-D-glucofuranose.

(b) Explain mutarotation using glucose as the example.

20. (a) Write the structures of ẞ-lactose and sucrose with appropriate labelling.

(b) Differentiate between amylose and amylopectin.

BCHCT 135 2025 - English

ASSIGNMENT

Solutions, Phase Equilibrium, Conductance, Electrochemistry & Functional Group Organic Chemistry-II

Core Course in Chemistry

Course Code: BCHCT-135 Assignment Code: BCHCT-135/TMA/2025

Maximum Marks: 100

PART-(A)

1. Discuss the effect of pressure on the solubility of gases. How is Henry's law constant determined?

2. Draw and explain the mutual solubility curve of nicotine-water system. Which other system exhibits the similar curve?

3. (a) What are conjugate solutions? Give one example.

(b) Define metastable equilibrium and differentiate it from true equilibrium

4. Define any five of the following terms:

(i) A component

(ii) Mole fraction

(iii) Incongruent melting compounds

(iv) Liquid junction potential

(v) Ionic mobility

(vi) Conductometric titration

5. (a) Give the mathematical expression for Gibbs phase rule and calculate the maximum number of phases that can coexist for a one-component system.

(b) Draw the phase diagram for sulphur system and label the sublimation and fusion curves for (3) monoclinic sulphur on it.

6.(a) How does a vs. T curves for a pure substance get affected by an increase in pressure? Draw a schematic diagram indicating the same?

(b) Two substances, X and Y form a simple eutectic system. The melting point of X is more than that of Y and a mixture of X and Y having 40% of X form the eutectic mixture having a melting point of 512 K. Based on this information, draw a schematic suitably labelled phase diagram for the system.

7.(a) Explain the concentration dependence of molar conductivity for a strong electrolyte

(b) The conductivity of a saturated solution of AgCl at 298 K was found to be 3.41 x 10'S cm 1. The water used for dissolving AgCl had a conductivity of 1.6 x 10'S cm. If the molar conductivity at infinite dilution for AgCl at 298 K is given as 138.2 S cm mol, calculate the solubility product of AgCl at 298 Κ.

8.(a) Describe the moving boundary method for the determination of transference numbers.

(b) In the determination of transference numbers of HCI by moving boundary method a 0.10 M solution of HCI was taken in a cell having uniform area of cross section of 1.0 cm². At the end of experiment the boundary moved by 10.3 cm and 0.132 g of silver was deposited on the cathode of silver coulometer. Calculate the transference numbers of ions of HCI.

9.(a) Outline the requirements for the construction of concentration cells without transference.

(b)The cell reaction for a galvanic cell is given below: Cu(s) + 2Ag (aq) →Cu(aq) + 2Ag(s)

(i) Write the half-cell reactions at the anode and the cathode.

(ii) Calculate the value of cell emf under standard conditions by using the data from Table 7.1.

(iii) Will the reaction be spontaneous as written?

10. (a)Define electrolysis and discuss any one application of electrolysis.

(b)Calculate the time required to get 5 g of magnesium by passing a current of 0.6 A through molten magnesium chloride. (Given: Mm(Mg) -24.25 g mol).

11. How will you prepare 2-methylpentanoic acid starting from a suitable alkyl halide? Write the sequence of reactions involved.

a) 12. Which alkyl halide will you use if pentanoic acid is to be obtained? Give the scheme of synthesis involved.

(b) Write the mechanism of amide formation using ethanoic acid and ammonia.

13. (a)What is transesterification? Briefly explain using a suitable example.

(b) Give the products formed when propyl butanoate is reduced using Bouveault-Blanc reduction. Which other reagent can be used to obtain the same products?

. (a) 14Using suitable diagram, explain the interconversion of enantiomers of N-methylethanamine.

(b) Explain why C-N bond in benzenamine is shorter than that in aliphatic amines.

15. (a)Which one is more stable-alkyl diazonium salt or an aryl diazonium salt? Explain.

(b) How can you obtain 4-methylbiphenyl from 4-methylbenzenaine? Write the reactions involved.

16. (a) Explain the Zwitter ionic nature and isoelectric point of a 2-amino acid.

(b) Discuss the chemistry of ninhydrin reaction of 2-amino acids and its importance

17. Discuss the N-protection and deprotection of amino acids using phathaloyl group.

18. Explain sanger method for the N-terminal identification of peptides giving suitable reactions.

19. What are reducing sugars? Which tests are exhibited by them? Give the chemistry of these tests.

20. How was structure of lactose arrived at? Explain. Also write the structure of its a-anomer.

BCHCT 135 2025 - Hindi

शिक्षक जांच सत्रीय कार्य

विलयन, प्रावस्था साम्य, चालकत्व, वैद्युत्-रसायन और अभिलक्षकीय समूह कार्बनिक रसायन-।।

रसायन विज्ञान का मूल पाठ्यक्रम

पाठ्यक्रम कोड: BCHCT-135

सत्रीय कार्य कोड: BCHCT-135/TMA/2025

अधिकतम अंक: 100

नोट: सभी प्रश्नों के उत्तर दीजिए। प्रश्नों के समान दायीं ओर कोष्ठक में दिए गए हैं।

भाग-(क)

1. गैसों की विलेयता पर दाब के प्रभाव की चर्चा कीजिए। हेनरी स्थिरांक किस प्रकार निर्धारित किया जाता है?

2. (क) निकोटिन-जल तंत्र के लिए पारस्परिक विलेयता वक्र आरेखित कीजिए और उसकी व्याख्या कीजिए। ऐसा कौन-सा एक अन्य तंत्र है जो ऐसा ही वक्र दर्शाता है?

3. (क) संयुग्मी विलयन क्या होते हैं? उनका एक उदाहरण दीजिए।

(ख) मितस्थायी साम्य को परिभाषित कीजिए तथा सत्य साम्य से इसका अंतर स्पष्ट कीजिए।

4. निम्नलिखित में से किन्हीं पांच की परिभाषा दीजिए।

(i) घटक

(ii) मोल अंश

(iii) अधूरा पिघलना

(iv) द्रव जंक्शन क्षमता

(v) आयनिक गतिशीलता

(vi) चालकतामितीय अनुमापन

5. (क) गिब्स के प्रावस्था नियम का गणितीय व्यंजक लिखिए तथा किसी एकल-घटक तंत्र के लिए एक साथ विद्यमान हो सकने वाली प्रावस्थाओं की अधिकतम संख्या को परिकलित कीजिए

(ख) सल्फर तंत्र के लिए प्रावस्था आरेख बनाएं तथा एकनताक्ष सल्फर के लिए ऊर्ध्वपातन तथा संगलन वक्रों को उस परदर्शाएं।

6. (क) किसी शुद्ध पदार्थ के लिए $mu$ और T के बीच वक्र दाब में परिवर्तन से किस प्रकार प्रभावित μ होता है? इसे दर्शाते हुए एक व्यवस्थात्मक चित्र बनाएं।

(ख) दो पदार्थ X तथा Y एक सरल यूटेक्टिक तंत्र बनाते हैं। X का गलनांक Y के गलनांक की तुलना में अधिक हैं तथा 40% X वाला X व Y का मिश्रण, यूटेक्टिक मिश्रण बनाता है जिसका गलनांक 512 K है। इस जानकारी के आधार पर तंत्र के लिए प्रावस्था आरेख का उपयुक्त नामांकित व्यवस्थात्मक चित्र बनाइए।

7. (क) एक प्रबल विद्युत्-अपघट्य के लिए मोलर चालकता की सांद्रता पर निर्भरता की व्याख्या कीजिए।

(ख) 298 K पर AgCl के संतृप्त विलयन की चालकता 3.41 x 10^-6 cm^-1 पाई गई। AgCl को घोलनें में प्रयुक्त जल की चालकता 1.06 x 10^-6 cm^-1 थी। यदि 298 K पर AgCl के लिए अनंत तनुता पर मोलर चालकता 138.2 S cm^-1 है तो 298 K पर AgCl का विलेयता गुणनफल परिकलित कीजिए।

8. (क) अभिगमनांकों के निर्धारण की चल-सीमाविधि का विवरण दीजिए।

(ख) चल-सीमाविधि द्वारा HCI के अभिगमनांकों के निर्धारण के लिए HCI के 0.10 M विलयन को सेल में लिया गया जिसकी अनुप्रस्थ काट क्षेत्रफल 1.0 cm² था। प्रयोग के अंत में सीमा ने 10.3 cm सीएम की दूरी तय की तथा कूलॉमीटर के कैथोड़ पर 0.132 g सिल्वर निक्षेपित हुआ। HCI के आयनों के अभिगमनांक परिकलित कीजिए।

9. (क) अभिगमन रहित सांद्रता सेलों के विनिर्माण की आवश्यकताओं को बताइए।

(ख) एक गैल्वैनी सेल की सेल अभिक्रिया नीचे दी गई है:

Cu(s) + 2Ag+(aq) →Cu²+(aq) + 2Ag(s)

(i) ऐनोड़ तथा कैथोड़ पर होनेवाली अर्ध-सेल अभिक्रियाएं लिखें।

(ii) सारणी 7.1 में दिए डाटा के आधार पर मानक अवस्थाओं में सेल emf का मान परिकलित कीजिए।

(iii) क्या ऊपर लिखी सेल अभिक्रिया स्वतः होगी ?

10. (क) विद्युत अपघटन को परिभाषित कीजिए तथा इसके किसी एक अनुप्रयोग की चर्चा कीजिए।

(ख) 5g मैग्नीशियम प्राप्त करने के लिए द्रवित मैग्नीशियम क्लोराइड में कितने समय तक 0.65 A की विद्युत् धारा को प्रवाहित करना होगा?

भाग-(ख)

11. आप किसी उचित ऐल्किल हैलाइड से आरंभ करके 2-मेथिलपेन्टेनोइक अम्ल किस प्रकार प्राप्त कर सकते हैं? इसमें निहित अभिक्रियाओं के क्रम को लिखिए।

12. (क) यदि आपको पेन्टेनोइक अम्ल प्राप्त करना हो तो आप किस ऐल्किल हैलाइड का उपयोग करेंगे? संश्लेषण में निहित अभिक्रियाओं को भी दीजिएब

(ख) एथेनाइक अम्ल और अमोनिया के उपयोग द्वारा ऐमाइड बनने की क्रियाविधि लिखिए।

13. (क) विपक्ष एस्टरीकरण क्या होता है? उचित उदाहरण द्वारा संक्षेप में व्याख्या कीजिए।

(ख) जब प्रोपिल ब्यूटेनोऐट को बूवो-ब्लांक अपचयन द्वारा अपचयित किया जाता है तो प्राप्त उत्पाद बताइए। ऐसा अन्य कौन-सा अभिकर्मक है जिसके उपयोग द्वारा समान उत्पाद प्राप्त होते हैं?

14. (क) उचित चित्र के उपयोग द्वारा N-मेथिलएथेनैमीन के ऐनैन्टिओमरो के अंतरारूपांतरण की व्याख्या कीजिए।

(ख) व्याख्या कीजिए कि बेन्जीनैमीन में उपस्थित C-N आबंध ऐलिफैटिक ऐमीनों में उपस्थित सी-न आबंध से छोटा क्यों होता है?

15. (क) ऐल्किल डाइऐजोनियम लवण और ऐरिल डाइऐजोनियम लवण में से कौन-सा अधिक स्थायी है? व्याख्या कीजिए।

(ख) आप 4-मेथिलबेन्जीनैमीन से आरंभ करके 4-मेथिलबाइफेनिल किस प्रकार प्राप्त कर सकते हैं? निहित अभिक्रियाओं को भी लिखिए।

16.( क) किसी 2-ऐमीनो अम्ल की उभयाविष्ट प्रकृति तथा समविभव बिंदु की व्याख्या कीजिए।

(ख) 2-ऐमीनो अम्लों की निनहाइड्रिन अभिक्रिया के रसायन और उसके महत्व की चर्चा कीजिए।

17. थैलॉयल समूह के उपयोग द्वारा ऐमीनों अम्लों के न-रक्षण तथा विरक्षण की चर्चा कीजिए।

18.उचित अभिक्रियाएं देते हुए पेप्टाइडों के न-सिरे की पहचान के लिए सैंगर विधि की व्याख्या कीजिए।

19.अपचायी शर्कराएं क्या होती हैं? उनके द्वारा कौन-सा परीक्षण दिया जाता है? इन परीक्षणों में निहित रसायन की चर्चा कीजिए।

20. लैक्टोस की संरचना किस प्रकार ज्ञात की गई? व्याख्या कीजिए। इसके - ऐनोमर की संरचना भी लिखिए।

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Product Information

Course Name	Bachelor of Science
Course Code	BSCG
Subject Code	BCHCT 135
Subject	Solutions, Phase equilibrium, Conductance, Electrochemistry and Functional Group Organic Chemistry-I
Programme	BACHELOR DEGREE PROGRAMMES Courses
Language	English
Material Type	Solved Assignment – Soft Copy / PDF

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