IGNOU BCHCT 135 2026 - Schmidt rearrangement

Question

Schmidt rearrangement

01 Dec 2025

Answer :

Word Count : 221

Schmidt rearrangement is an important reaction in Functional Group Organic Chemistry-I where an acyl compound reacts with hydrazoic acid or azide reagents to form amides with loss of nitrogen gas. When carboxylic acids or their derivatives like acid chlorides or anhydrides are treated with hydrazoic acid in the presence of a strong acid such as H2SO4, rearrangement occurs with migration of an alkyl or aryl group from carbonyl carbon to the electron-deficient nitrogen,

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