Question

reason for the following: 

(a) Mercury (II) iodide is brick red in colour.

(b) The aqueous solution of NiSO4 which is pale green turns deep blue on addition of ethylenediamine.

25 Jan 2018
Answer :
Word Count : 199

(a). Mercury (II) iodide is brick red in colour because Mercury(II) iodide displays thermochromism; when heated above 126 °C (400°K) it undergoes a phase transition, from the red alpha crystalline form to a pale yellow beta form. As the sample cools, it gradually reacquires its original colour. It has often used for thermochromism demonstrations. A third orange form is also known; this can be formed by recrystallisation and is also metastable, eventually converting

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