Chemical properties of soil are -

1. The chemical qualities of soils change with time

The weathering of the parent material by water determines, to a large extent, the chemical composition of the soil which has ultimately been produced. Some chemicals are leached* into the lower soil layers where they accumulate. Other chemicals, more insoluble, are left in the upper layers of the soil. The most rapid removed chemicals are chlorides and sulphates, followed by calcium, sodium, magnesium and potassium.

The silicates and oxides of iron and aluminium decompose very slowly and are rarely leached*. When some of these products come into contact with the air in the soil, chemical reactions occur, such as oxidation in particular, which results in the formation of chemicals either more soluble or more fragile than the original ones. This results in an acceleration of the weathering processes, increased leaching* of chemicals, and further changes in the soil chemical composition.

A freshwater acid sulphate soil (see Section 1.8) may develop when the waterlogged soil containing iron sulphurs (pyrites) is exposed to the air, for example, when constructing ponds. Oxidation of the pyrites takes place and acidification of the soil occurs. The pond water may then become too acid for fish culture.

The air present in the soil also contains carbon dioxide. This gas combined with water can form a weak acid (carbonic acid) which will then react with some of the soil chemicals to form new ones.

2.The chemical reaction of the soil (pH)

does pH mean?

Soils may have either an acid or an alkaline reaction, or may be neutral. The measure of the chemical reaction of the soil is expressed by its pH value. The pH value varies from 0 to 14, with pH = 7 indicating that the soil has a neutral reaction. Values smaller than 7 indicate acidity and values greater than 7 indicate alkalinity. The further from the neutral point, the greater the acidity or the alkalinity.

How do you measure pH?

The most accurate method of determining soil pH is by means of an electrical pH meter which gives a direct reading of the pH value when glass electrodes are inserted in a solution obtained by mixing one part of the soil sample with two parts of distilled water. Such equipment is available in soil testing laboratories.

As a general indication of the soil pH, litmus paper and colour indicators can be used in the field. Litmus paper which turns red in acid conditions and blue in alkaline conditions is relatively cheap and may usually be bought from a chemist. It is partly dipped in a soil suspension made by mixing one part of soil with two parts of distilled water or,