"A kinetically stable supramolecular complex may not always be the thermodynamically most stable product". Justify this statement.
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What is bis(tren)? Draw its structure and the structure of its smaller analogue. Discuss important features of its bonding with different anions.
Which cations will fit into these crown ethers?
(2) 
Discuss the important factors which may be considered when one designs a molecular receptor for selective binding of a guest molecule.
Explain the different types of cooperativity in supramolecular chemistry. Also give suitable examples (one each) for each type.
Explain entropic hydrophobic effect. What is its role in supramolecular chemistry?
What are cyclodextrins? Name three important cyclodextrins. Also give their constituent units and the type of bonds present in them.
"Supramolecualar systems have been designed to mimic the structure or function of more complex biological processes". Explain this with any two examples.